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The Basic Principles Of Circularly Polarized Luminescence
The second reaction cycle in NO synthesis involves O2 binding to ferrous NOS to form the Fe, IIO2 intermediate, followed by oxidation of NOHA to generate ferric enzyme, NO, citrulline, and water as products (Fig. 9) - circular dichroism. As attracted Fig - https://nowewyrazy.uw.edu.pl/profil. 9, the reaction might also include electron transfer from H4B to the Fe, IIO2 intermediate
l9 As displayed in Fig. 9, this could be since the H4B radical serve as an sites electron sink in a later point in the response, so as to permit NOS to, Fig. 9. A model for NORA oxidation by NOSoxy in the single turnover response. Oxygen binds to the ferrous protein to form the Fe, IIO2 species, which upon receiving an electron from H4B forms a putative hemeperoxo intermediate that responds with NOHA.